The Rotational Spectrum and Molecular Structure of Chlorine Chlorate
Identifieur interne : 000725 ( Main/Exploration ); précédent : 000724; suivant : 000726The Rotational Spectrum and Molecular Structure of Chlorine Chlorate
Auteurs : R. R. Friedl [États-Unis] ; M. Birk [États-Unis] ; J. J. Oh [États-Unis] ; E. A. Cohen [États-Unis]Source :
- Journal of Molecular Spectroscopy [ 0022-2852 ] ; 1995.
Abstract
Cl2O3 has been identified as a product of the ClO + OClO + M reaction at 220 K using submillimeter spectroscopy of the reaction products in a flowing gas mixture. The spectra of all four Cl isotopic species have been observed in the 415-436 GHz region. Selected transitions have also been measured at frequencies down to 209 GHz. The rotational and centrifugal distortion constants have been determined for all four species. The quadrupole splittings have been fitted for the main species. Structural parameters similar to those of other chlorine oxides have been derived from the rotational constants. These and the quadrupole coupling constants are consistent with those expected from a chlorine chlorate structure with no planes of symmetry. Structures which satisfy the requirement inferred from published infrared data that the Cl[]O bonds must be shorter than those in OClO must all have long single bonds between the ClO and OClO portions of the molecule.
Url:
DOI: 10.1006/jmsp.1995.1079
Affiliations:
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">The Rotational Spectrum and Molecular Structure of Chlorine Chlorate</title><author><name sortKey="Friedl, R R" sort="Friedl, R R" uniqKey="Friedl R" first="R. R." last="Friedl">R. R. Friedl</name></author><author><name sortKey="Birk, M" sort="Birk, M" uniqKey="Birk M" first="M." last="Birk">M. Birk</name></author><author><name sortKey="Oh, J J" sort="Oh, J J" uniqKey="Oh J" first="J. J." last="Oh">J. J. Oh</name></author><author><name sortKey="Cohen, E A" sort="Cohen, E A" uniqKey="Cohen E" first="E. A." last="Cohen">E. A. Cohen</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:4A9512C368BE13C0460C9A0DFF41C9F8A552874A</idno><date when="1995" year="1995">1995</date><idno type="doi">10.1006/jmsp.1995.1079</idno><idno type="url">https://api.istex.fr/document/4A9512C368BE13C0460C9A0DFF41C9F8A552874A/fulltext/pdf</idno><idno type="wicri:Area/Main/Corpus">000069</idno><idno type="wicri:Area/Main/Curation">000069</idno><idno type="wicri:Area/Main/Exploration">000725</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Exploration">000725</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">The Rotational Spectrum and Molecular Structure of Chlorine Chlorate</title><author><name sortKey="Friedl, R R" sort="Friedl, R R" uniqKey="Friedl R" first="R. R." last="Friedl">R. R. Friedl</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Caltech, Jet Prop Lab, Pasadena, CA 91109</wicri:regionArea><wicri:noRegion>CA 91109</wicri:noRegion></affiliation></author><author><name sortKey="Birk, M" sort="Birk, M" uniqKey="Birk M" first="M." last="Birk">M. Birk</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Caltech, Jet Prop Lab, Pasadena, CA 91109</wicri:regionArea><wicri:noRegion>CA 91109</wicri:noRegion></affiliation></author><author><name sortKey="Oh, J J" sort="Oh, J J" uniqKey="Oh J" first="J. J." last="Oh">J. J. Oh</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Caltech, Jet Prop Lab, Pasadena, CA 91109</wicri:regionArea><wicri:noRegion>CA 91109</wicri:noRegion></affiliation></author><author><name sortKey="Cohen, E A" sort="Cohen, E A" uniqKey="Cohen E" first="E. A." last="Cohen">E. A. Cohen</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Caltech, Jet Prop Lab, Pasadena, CA 91109</wicri:regionArea><wicri:noRegion>CA 91109</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Molecular Spectroscopy</title><title level="j" type="abbrev">YJMSP</title><idno type="ISSN">0022-2852</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1995">1995</date><biblScope unit="volume">170</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="383">383</biblScope><biblScope unit="page" to="396">396</biblScope></imprint><idno type="ISSN">0022-2852</idno></series><idno type="istex">4A9512C368BE13C0460C9A0DFF41C9F8A552874A</idno><idno type="DOI">10.1006/jmsp.1995.1079</idno><idno type="PII">S0022-2852(85)71079-X</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-2852</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Cl2O3 has been identified as a product of the ClO + OClO + M reaction at 220 K using submillimeter spectroscopy of the reaction products in a flowing gas mixture. The spectra of all four Cl isotopic species have been observed in the 415-436 GHz region. Selected transitions have also been measured at frequencies down to 209 GHz. The rotational and centrifugal distortion constants have been determined for all four species. The quadrupole splittings have been fitted for the main species. Structural parameters similar to those of other chlorine oxides have been derived from the rotational constants. These and the quadrupole coupling constants are consistent with those expected from a chlorine chlorate structure with no planes of symmetry. Structures which satisfy the requirement inferred from published infrared data that the Cl[]O bonds must be shorter than those in OClO must all have long single bonds between the ClO and OClO portions of the molecule.</div></front></TEI><affiliations><list><country><li>États-Unis</li></country></list><tree><country name="États-Unis"><noRegion><name sortKey="Friedl, R R" sort="Friedl, R R" uniqKey="Friedl R" first="R. R." last="Friedl">R. R. Friedl</name></noRegion><name sortKey="Birk, M" sort="Birk, M" uniqKey="Birk M" first="M." last="Birk">M. Birk</name><name sortKey="Cohen, E A" sort="Cohen, E A" uniqKey="Cohen E" first="E. A." last="Cohen">E. A. Cohen</name><name sortKey="Oh, J J" sort="Oh, J J" uniqKey="Oh J" first="J. J." last="Oh">J. J. Oh</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Amerique/explor/CaltechV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000725 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000725 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Amerique
|area= CaltechV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:4A9512C368BE13C0460C9A0DFF41C9F8A552874A
|texte= The Rotational Spectrum and Molecular Structure of Chlorine Chlorate
}}
| This area was generated with Dilib version V0.6.32. |  |